Knowledge of Nickel Alloys
Time:
2024-10-24
Introduction to Nickel Alloys
Nickel alloys are alloys composed of nickel-based additions of other elements. Nickel has good mechanical, physical and chemical properties. Adding appropriate elements can improve its oxidation resistance, corrosion resistance, high temperature strength and improve some physical properties.
Classification and Characteristics of Nickel-Based Alloys
Nickel-based alloys refer to a class of alloys that have comprehensive properties such as high strength and certain oxidation and corrosion resistance at high temperatures of 650 to 1000 °C. According to the main properties, it is subdivided into nickel-based superalloys, nickel-based corrosion-resistant alloys, nickel-based wear-resistant alloys, nickel-based precision alloys and nickel-based shape memory alloys.
1. Nickel-based superalloys
The main alloying elements are chromium, tungsten, molybdenum, cobalt, aluminum, titanium, boron, zirconium, etc. Among them, chromium plays the role of anti-oxidation and anti-corrosion, and other elements play a strengthening role. It has high strength, oxidation resistance, and gas corrosion resistance at high temperatures of 650 to 1000 °C. It is mainly used in the manufacture of high-temperature components for aero-engine blades and rocket engines, nuclear reactors, and energy conversion equipment.
2. Nickel-based corrosion-resistant alloys
The main alloying elements are copper, chromium and molybdenum. It has good comprehensive properties and is resistant to various acid corrosion and stress corrosion. The earliest application was nickel-copper alloy, also known as Monel alloy; in addition, nickel-chromium alloy, nickel-molybdenum alloy, nickel-chromium-molybdenum alloy, etc. It is used for the manufacture of various corrosion-resistant parts.
3. Nickel-based wear-resistant alloys
The main alloying elements are chromium, molybdenum, tungsten, and also contain small amounts of niobium, tantalum and indium. In addition to its wear resistance, it has good oxidation resistance, corrosion resistance and welding performance. It can be used to manufacture wear-resistant parts, and can also be used as a cladding material to coat the surface of other base materials through surfacing and spraying processes.
4. Nickel-based precision alloys
Including nickel-based soft magnetic alloys, nickel-based precision resistance alloys and nickel-based electrothermal alloys, etc. The most commonly used soft magnetic alloys are permalloys containing about 80% of nickel. They have high maximum and initial permeability and low coercivity. They are important core materials in the electronics industry. The main alloying elements of nickel-based precision resistance alloys are chromium, aluminum, and copper. This alloy has high resistivity, low temperature coefficient of resistivity and good corrosion resistance, and is used to make resistors. Nickel-based electrothermal alloy is a nickel alloy containing 20% chromium, which has good anti-oxidation and anti-corrosion properties, and can be used for a long time at a temperature of 1000-1100 °C.
5. Nickel-based shape memory alloys
A nickel alloy containing 50(at)% of titanium. The rewarming temperature is 70°C, and the shape memory effect is good. A small change in the nickel-titanium composition ratio can change the rewarming temperature within the range of 30 to 100 °C. It is mostly used in the manufacture of self-expanding structural parts used in spacecraft, self-energizing fasteners used in the aerospace industry, and artificial heart motors used in biomedicine.
Application Fields of Nickel-Based Alloys
The development level of the nickel-based alloy industry is in a steady upward trend. Nickel-based alloys with different compositions and different properties have been widely used with industrial development. The main application areas are:
1. Ocean: marine structures in the marine environment, seawater desalination, seawater aquaculture, seawater heat exchange, etc.
2. Environmental protection field: flue gas desulfurization device for thermal power generation, waste water treatment, etc.
3. Energy field: nuclear power generation, comprehensive utilization of coal, ocean tide power generation, etc.
4. Petrochemical field: oil refining, chemical and chemical equipment, etc.
5. Food field: salt making, soy sauce brewing, etc.
Latest News
Nickel-Chromium and Nickel-Chromium-Iron alloy wire
Nickel chromium and nickel chromium iron alloy are the most widely used high resistance electric heating alloys. This alloy has high resistivity, good oxidation resistance and wear resistance, good machining performance and welding performance, and high strength at high temperatures. The alloy is suitable for manufacturing heating elements, voltage regulating resistors and braking resistors of various motors in metallurgy, chemical industry, machinery, glass, ceramics, household appliances and other industrial sectors.
Copper copper nickel thermocouple wire (T type)
Copper copper nickel thermocouple (T-type thermocouple), also known as copper constantan thermocouple, is the best low temperature low metal thermocouple. Its positive pole (TP) is pure copper, and its negative pole (TN) is copper nickel alloy, often called constantan. It is common with the EN of nickel chromium constantan and cannot be common with the JN of iron constantan, although they are all called constantan. The measuring temperature range of copper copper nickel thermocouple is - 200~350 ℃.
Iron copper nickel (constantan) thermocouple wire (J)
Iron copper nickel thermocouple (J-type thermocouple) is also called iron constantan thermocouple. The nominal chemical composition of its positive pole (JP) is pure iron, and the negative pole (JN) is copper nickel alloy, which is often vaguely called constantan. Its nominal chemical composition is 55% copper, 45% nickel, and a small amount of very important cobalt, iron, manganese and other elements. Although it is called constantan, it is different from nickel chromium constantan and copper constantan, so it cannot be replaced by EN or TN. The temperature range covered by iron constantan thermocouple is - 210~1200 ℃, but the commonly used temperature range is 0-750 ℃.
Ni Cr Si Ni Si Mg thermocouple wire (N type)
The nickel chromium silicon nickel silicon magnesium thermocouple (N-type thermocouple) is a low metal thermocouple, which is the latest internationally standardized thermocouple. The nominal chemical composition of the positive pole (NP) is: Ni: Cr: Si ≈ 84.4:14.2:1.4, and the nominal chemical composition of the negative pole (NN) is: Ni: Si: Mg ≈ 95.5:4.4:0.1. Its use temperature range is - 200~1300 ℃.
Nickel chromium copper nickel (constantan) thermocouple wire (type E)
Nickel chromium copper nickel thermocouple (E-type thermocouple), also known as nickel chromium constantan thermocouple, is also a kind of low metal thermocouple. Its positive electrode (EP) is nickel chromium 10 alloy with the same chemical composition as KP. The negative electrode (EN) is copper nickel alloy. Its nominal chemical composition is 55% copper, 45% nickel and a small amount of cobalt, manganese, iron and other elements. The use temperature of the thermocouple is - 200~900 ℃.
Nickel chromium nickel silicon thermocouple wire (Type K)
Nickel chromium nickel silicon thermocouple (K-type thermocouple) is the low metal thermocouple with the largest usage in the temperature measurement area above 500 ℃, and its usage is the sum of other metal thermocouples. The nominal chemical composition of the positive pole (KP) is Ni: Cr ≈ 90:10, and the chemical composition of the negative pole (KN) is Ni: Si ≈ 97:3, and its operating temperature range is - 200~1300 ℃.
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